Tea chemistry
What is actually in a tea leaf, what each compound does in the cup, which processing step creates or destroys it, and which brewing decision brings it out. One plant makes six categories of tea, and this is the level at which that stops being surprising.
Two words this section refuses to confuse
Bitterness is a taste. It is registered on the tongue, it comes largely from caffeine and from the catechins without a gallate group, and it is reduced by brewing cooler.
Astringency is a tactile sensation. The mouth dries and the surfaces stop sliding, because polyphenols have associated with the proteins in saliva and taken them out of solution. It is reduced by shortening contact and by not agitating the leaf.
Tea writing merges the two constantly, and the merge is not harmless: the two have different causes and different remedies, so a drinker who has learned them as one thing will reach for the wrong fix about half the time. Every record here declares which of them a compound produces, and a rule refuses to publish one whose prose crosses the line its own declaration draws.
What this section does not do
These pages describe what a compound does in the leaf and in the cup — where it occurs, what processing does to it, how it extracts, what it tastes, smells or feels like, what colour it makes. They do not describe what any compound does in a body. That is a different question, TeaHQ holds it pending a review that no source on this site has been countersigned for, and it is not answered anywhere in this section — not hedged, not sourced, not in passing. Every record states its own version of that refusal in its own words.
Methylxanthines
Tea's alkaloids. Bitter, fast to extract, barely touched by processing — and the group most often blamed for a sensation it does not cause.
Tea's principal alkaloid, bitter at concentration, and the compound most often blamed for a drying sensation it does not cause.
The minor methylxanthine, present in every tea and dominant in none — the reason a tea leaf is not a one-alkaloid plant.
The third methylxanthine, present in tea in trace amounts, and named after the plant despite being far more abundant elsewhere.
Amino acids
The savoury and sweet side of the balance. They extract in cool water where the polyphenols need heat, which is the single most useful fact in green tea brewing.
The second most abundant free amino acid in a heavily shaded tea, and the one that reveals how much nitrogen the field was given.
- Free amino acidsA family, not a single compound
The savoury half of the balance that decides whether a green tea tastes sweet or brisk — and half of the ratio Chinese graders actually use.
The compound an entire tea category is named and sold on, and the one thing in that category a drinker cannot taste.
The compound umami was defined from, present in tea in free form and responsible for the part of a savoury cup that tastes like stock rather than like tea.
The savoury amino acid that makes shaded green tea taste like broth, and the compound that explains why shading exists at all.
Catechins
The largest soluble group in green tea and the source of astringency. Not tannins, and not what makes a cup bitter.
- CatechinsA family, not a single compound
The largest soluble fraction of a green tea leaf, the source of astringency, and the compounds oxidation turns into everything a black tea is.
The other galloylated catechin, and weight for weight the most drying thing in the leaf.
The catechin without a gallate group — bitter more than drying, and the partner EGCG needs to make a theaflavin.
The most abundant catechin in green tea, and the clearest single demonstration that astringency and bitterness are different things.
The smallest and mildest tea catechin, present in cocoa and apples as well, and the other half of a simple theaflavin.
- Epimerised catechinsA family, not a single compound
What roasting actually does to a tea's catechins: not destroys them, flips them. The same molecules, mirrored at one carbon, sitting differently on the tongue.
- Methylated catechinsA family, not a single compound
A small family of catechin variants that a handful of Japanese cultivars carry unusually — and the clearest case on this site of a compound famous for a reason TeaHQ will not discuss.
Oxidation polyphenols
What oxidation and fermentation build from catechins. None of these exists in a fresh leaf; every one of them is made.
- Tea creamA family, not a single compound
The cloud that forms in a black tea as it cools. Not a fault, not hard water, and the single most misdiagnosed thing that happens in a glass of iced tea.
- TheabrowninsA family, not a single compound
The dark, water-soluble polymers of ripe pu-erh and other dark teas — why a shou is almost black and almost never drying.
- TheaflavinsA family, not a single compound
The bright orange-red pigments oxidation builds from catechins, and the compounds the tea trade means by briskness.
- ThearubiginsA family, not a single compound
The largest fraction of a black tea liquor, responsible for its depth and body, and not actually a compound at all.
- TheasinensinsA family, not a single compound
The dimers formed when two catechins of the same type couple — the oxidation route oolong takes and black tea largely does not.
Flavonols
Present in small amounts and detectable in very small ones. A large part of why total polyphenol figures predict mouthfeel so poorly.
- Flavonol glycosidesA family, not a single compound
Present in small amounts, detectable at very low ones, and a large contributor to the velvety, mouth-coating dryness catechins alone do not explain.
Phenolic acids
Small acids released as larger polyphenols come apart — markers of how far a dark tea has travelled.
The gallate group after it has been separated from its catechin — small, sour, drying, and a marker of how far a dark tea has fermented.
A minor acid that contributes to mouthfulness — the sense that a liquor has substance rather than merely strength.
Terpenoid aroma compounds
Floral and fruity aroma, stored in the leaf bound to sugar and set free by withering and bruising. Floral is a family here, never one compound.
Stewed fruit, rose and honey at a level almost nothing else in tea can match, and the compound most often handed sole credit for muscatel.
Violet and dried-fruit aroma from broken-down carotenoid pigment, detectable at some of the lowest levels in tea.
A principal source of rose character in tea, and half of the clearest compositional difference between China-type and Assam-type plants.
A major floral aroma compound of tea, largely stored bound to sugar in the leaf and set free by processing.
- Linalool oxidesA family, not a single compound
What linalool becomes when the leaf is oxidised — sweeter, creamier and less sharply floral, and a marker of how far a tea has gone.
A woody-floral aroma compound that rises when the leaf is stressed — by bruising, and famously by insects.
Green-leaf volatiles
The smell of cut grass, made within seconds of the leaf being damaged, and the aroma most of tea manufacture exists to remove.
Leaf alcohol: the specific compound behind the smell of freshly cut grass, and the one a tea maker is judging when they smell a withering trough.
- Green-leaf volatilesA family, not a single compound
The smell of cut grass, made within seconds of the leaf being damaged, and the aroma most of tea processing exists to get rid of.
Esters and lactones
Creamy, minty and stone-fruit notes — some the plant's own, some carried across from flowers during scenting.
A creamy, peach-and-jasmine note that arrives in tea both from scenting with real flowers and from the leaf's own chemistry.
The wintergreen and minty-medicinal note of some Darjeelings and oolongs — a plant stress signal that ends up in the cup.
Benzenoid aroma compounds
Rose and honey, built from an amino acid rather than from a terpene. A different origin from the florals it is constantly merged with, and the origin is what moves with processing.
Rose and honey, built from an amino acid. Filed with the terpenoid florals everywhere in tea writing, and moved by an entirely different set of steps.
Nitrogen aroma compounds
Jasmine at trace level and roast aroma after heat. The two clearest cases in tea of dose deciding identity.
Jasmine at trace level and something much worse above it — the clearest demonstration in tea that dose decides identity.
- PyrazinesA family, not a single compound
The roasted, nutty and toasted aromas — compounds that do not exist in a tea leaf until heat makes them.
Malt and roast aldehydes
Malt. Made when heat degrades the leaf's own amino acids alongside its sugars, which is why the maltiest teas are the ones with the most amino acid to spend.
- Strecker aldehydesA family, not a single compound
Malt. The group made when firing spends the leaf's own amino acids against its own sugars, and the reason the maltiest teas are the ones with the most amino acid to spend.
Sulfur aroma compounds
The marine and nori note of shaded Japanese tea — an aroma, not a taste.
The nori and seaside note of good Japanese green tea — and the compound umami is routinely mistaken for.
Smoke phenols
Smoke, and the one defining compound in tea that the plant did not make.
The smell of smoke, deposited on the leaf from burning pinewood — the compound that makes Lapsang Souchong what it is.
Pigments
Why leaf and liquor look the way they do — including why a steeped green tea is yellow and only a whisked one is green.
- AnthocyaninsA family, not a single compound
The purple of purple tea — water-soluble, unlike the other pigments here, and it changes colour with the acidity of the water.
- CarotenoidsA family, not a single compound
The yellow-orange pigments hidden under the green — and the raw material for a good part of tea's fruit and floral aroma.
- ChlorophyllA family, not a single compound
The green of the leaf, and — because it barely dissolves — the reason a steeped green tea is yellow while a whisked one is green.
- MelanoidinsA family, not a single compound
The brown that heat makes. Why a roasted tea pours darker than the green tea it was, and why that darkness has nothing to do with oxidation.
- PheophytinA family, not a single compound
What chlorophyll becomes when heat or acid knocks the magnesium out — and the whole explanation for green tea going olive.
Sugars and polysaccharides
Small amounts of sugar, tasted faintly and indispensable to roast aroma; and the polysaccharides behind thickness.
- PectinsA family, not a single compound
The cell-wall polysaccharides behind thickness and slipperiness — the quality Chinese tasters call hou and English-language tasting notes struggle to name.
- Soluble sugarsA family, not a single compound
Present in small amounts, tasted only faintly, and indispensable as the fuel for every roasted aroma in tea.
Leaf lipids
Nothing a drinker tastes directly, and the raw material for the aroma they taste first. Also the fraction that goes off, which is what staling in a green tea actually is.
- Leaf lipidsA family, not a single compound
The fraction a drinker never tastes and cannot do without: the raw material every green-leaf aroma is cut from, and the part of the leaf that goes off.
Organic acids
The sourness axis, and the reason a squeeze of lemon changes a cup's colour without changing its strength.
- Organic acidsA family, not a single compound
The sourness axis, and the reason a tea liquor is mildly acidic — which decides what colour it is as much as what it tastes like.
Saponins
Surface-active compounds — the foam on whisked matcha, and a catch at the back of the throat.
- Tea saponinsA family, not a single compound
The surface-active compounds that make matcha foam and a poured cup froth — and a small, throat-catching bitterness alongside.
Minerals
Soil elements accumulated with leaf age. None of them is detectable in a cup, and this site says nothing about them beyond composition and extraction.
The tea plant is one of the few crops that accumulates aluminium, and most of what it accumulates never reaches the cup.
A soil ion the tea plant accumulates steadily with leaf age — which is why the coarsest teas carry the most and buds carry the least.
One of the elements tea is genuinely notable for accumulating, and — like the others — invisible in the cup.
Where these pages connect
Chemistry is only useful here because it joins two things the rest of the site already holds. Every compound names the processing steps that create or destroy it, and every one states how brewing decisions change how much of it reaches the cup. If a page tells you nothing you could act on at the kettle, it should not exist.